Current work on connectionist models has been focused largely on artificial neural networks that are inspired by the networks of biological neurons in the human brain. However, there are also other connectionistarchitectures that differ significantly from this biological exemplar. We proposed a novel connectionist learning architecture inspired by the physics associated with optical coatings of multiple layers of thin-films in a previous paper (Li and Purvis 1999, Annals of Mathematics and Artificial Intelligence, 26: 1-4). The proposed model differs significantly from the widely used neuron-inspired models. With thin-film layer thicknesses serving as adjustable parameters (as compared with connection weights in a neural network) for the learning system, the optical thin-film multilayer model (OTFM) is capable of approximating virtually any kind of highly nonlinear mappings. The OTFM is not a physical implementation using optical devices. Instead, it is proposed as a new connectionist learning architecture with its distinct optical properties as compared with neural networks. In this paper we focus on a detailed comparison of neural networks and the OTFM (Li 2001, Proceedings ofINNS-IEEE International Joint Conference on Neural Networks, Washington, DC, pp. 1727-1732). We describe the architecture of the OTFM and show how it can be viewed as a connectionist learning model. We then present experimental results on solving a classification problem and a time series prediction problem that are typical of conventional connectionist architectures to demonstrate the OTFM's learning capability.