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CRYSTAL GROWTH AND THE SEARCH FOR HIGHLY CORRELATED INTERMETALLICS 

Authors: Evan Lyle Thomas a;  Jasmine N. Millican a;  Edem K. Okudzeto a; Julia Y. Chan a
Affiliation:   a Department of Chemistry, Louisiana State University, Baton Rouge, LA, USA
DOI: 10.1080/02603590600666215
Publication Frequency: 6 issues per year
Published in: journal Comments on Inorganic Chemistry, Volume 27, Issue 1 & 2 August 2006 , pages 1 - 39
Formats available: HTML (English) : PDF (English)
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Abstract

Our interests lie in studying and understanding the structure-property relationships in novel ternary intermetallics synthesized by metallic flux-growth methods. This review highlights the synthesis, structures and physical properties of ternary lanthanide - transition metal - main group element intermetallics (Ln - T - X), where T = Co, Rh, Ir, Ni, Pd, and Pt, and X = Ga, In, Sb and Sn. Several phases will be discussed, including LnnTIn3n+2 (n = 1, 2, ∞), CePdGa6, Ce2PdGa12, Ce2PdGa10, LnNiSb3, LnNi1-xSb2 (x ∼ 0.4) and Ln3Co4Sn13. In addition, we report the synthesis, structure characterization, and magnetic behavior from single crystals of Ln3Co4Sn13 (Ln = Pr, Nd, Sm, Gd, Tb).
Keywords: heavy fermion; superconductivity; magnetism; heat capacity; electrical resistivity; rare earth intermetallics; single crystal; flux growth; indides; gallides; antimonides; stannides; CeCoIn5; CeRhIn5; CeIrIn5; Ce2CoIn8; Ce2RhIn8; Ce2IrIn8; CePdGa6; Ce2PdGa10; Ce2PdGa12; CeNiSb3; LnNiSb2; YNiSb2; Ln3Co4Sn13; Pr3Co4Sn13
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