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Hardness and elastic modulus of zircon as a function of heavy-particle irradiation dose: I. In situ agr-decay event damage 

Authors: B. C. Chakoumakos a;  W. C. Oliver b;  G. R. Lumpkin cd; R. C. Ewing c
Affiliations:   a Solid State Division Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA
b Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA
c Department of Geology, University of New Mexico, Albuquerque, New Mexico, USA
d Australia Nuclear Science and Technology Organization, Materials Division, New South Wales, Australia
DOI: 10.1080/10420159108220764
Publication Frequency: 12 issues per year
Published in: journal Radiation Effects and Defects in Solids, Volume 118, Issue 4 December 1991 , pages 393 - 403
Formats available: PDF (English)
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Abstract

For a natural single crystal of zircon, ZrSiO4, from Sri Lanka, exhibiting zonation in U and Th contents, the hardness and elastic modulus have been determined as a function of agr-decay dose using a mechanical properties microprobe (MPM). The zones vary in thickness from one to hundreds of micrometers, and have uranium and thorium concentrations such that the agr-decay dose varies between 2 times 1015 and 1 times 1016 agr-decay events/mg (0.15 to 0.65 dpa, displacement per atom). The transition from the crystalline to the aperiodic metamict state occurs over this dose range. For a traverse of 75 indent pairs across layers sampling a large portion of the crystalline-to-metamict transition (3.7 times 1015 to 9.7 times 1015 agr-decay events/mg) both the hardness and elastic modulus decrease linearly with increasing agr-decay dose. The radiation-induced softening follows a behavior similar to other radiation-induced changes, that is with the expansion of the unit cell parameters there is a decrease in density, birefringence, hardness and bulk modulus.
Keywords: agr-decay damage; crystalline-to-amorphous transition; elastic modulus; hardness; mechanical properties microprobe; metamict; zircon
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