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Polymeric, H-Bonded, and Chelatable Phenoxyl and Nitroxide Radicals
Authors:
Paul M. Lahti a;
Burak Esat a;
Jacqueline R. Ferrer a;
Yanbing Liu a;
Kenneth A. Marby a;
Chunping Xie a;
Clifford George b;
Guillermo Antorrena c;
Fernando Palacio c
| Affiliations: | a Department of Chemistry, University of Massachusetts, Amherst, MA, USA |
| b Laboratory for the Structure of Matter, Naval Research Laboratory, Washington, DC, USA | |
| c Instituto de Ciencia de Materiales de Aragon, CSIC - Universidad de Zaragoza, Zaragoza, SPAIN |
DOI:
10.1080/10587259908023326
First Published on:
01 September 1999
Subjects:
Chemistry;
Condensed Matter Physics;
Crystallography;
Inorganic Chemistry;
Materials Chemistry;
Organic Chemistry;
Physical Chemistry;
Formats available:
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(English)
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Abstract
Various examples are described of a multi-strategy approach to improvement of multispin exchange design. For example, H-bonded benzimidazole 4-t-butylnitroxide shows apparent simple planar 2D-type interaction, with a Weiss constant of Θ = -4.24 K and an intraplane exchange interaction of J = -1.60 K.
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| Keywords: hydrogen-bonding; magnetism; phenoxyl; nitroxide; polyradical |
| view references (19) |
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