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Distribution and Fractionation of Phosphorus, Cadmium, Nickel, and Lead in Calcareous Soils Amended with Composts 

Authors: Gladis M. Zinati a;  Yuncong Li b;  Herbert H. Bryan b;  Rao S. Mylavarapu c; Merlyn Codallo b
Affiliations:   a Department of Plant Biology and Pathology, Rutgers University, New Brunswick, New Jersey, USA
b Tropical Research and Education Center, University of Florida, Homestead, Florida, USA
c Soil and Water Science Department, University of Florida, Gainesville, Florida, USA
DOI: 10.1081/PFC-120027450
Publication Frequency: 8 issues per year
Published in: journal Journal of Environmental Science and Health, Part B, Volume 39, Issue 1 January 2005 , pages 209 - 223
Formats available: HTML (English) : PDF (English)
Also incorporating: Environmental Letters
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Abstract

Composts improve organic carbon content and nutrients of calcareous soils but the accumulation and distribution of phosphorus and heavy metals among various fractions in soil may vary under the south Florida conditions. The accumulation of P, Cd, Ni, and Pb with depth and the distribution of water soluble, exchangeable, carbonate, Fe-Mn oxides, organic and residual forms of each element were investigated in soils amended with municipal solid waste (MSW) compost, co-compost and biosolids compost and inorganic fertilizer (as control). Total concentrations of P, Cd, Ni, and Pb were higher in the 0-22 cm soil layers and decreased considerably in the rock layers. These elements were in the decreasing order of P 〉 Pb > Ni > Cd. Amounts of water soluble and exchangeable forms of P, Cd, Ni and Pb were negligible at 0-22 cm soil depths except for Cd in the 10-22 cm depth. Amending calcareous soil with either organic or inorganic amendments rendered phosphorus, nickle and lead in the residual form followed by Fe-Mn oxides form in the 0-10 and 10-22 cm soil layers. Cadmium was predominantly in the Fe-Mn oxides fraction followed by the residual and carbonate forms in both soil layers. A significant positive correlation was found between various organic carbon fractions and organic forms of P, Cd and Pb in the surface soil layer. Soil amended with MSW compost had higher concentration of Cd in the organic fraction whereas, co-compost and MSW compost amended soil had higher concentrations of organic Ni fraction in the 0-10 cm soil layer.
Keywords: Accumulation of metals; Biosolids; Co-compost; Fractionation of metals; Heavy metals; Municipal solid waste; Phosphorus; Soil organic carbon
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