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First Total Synthesis of (±)Hedaol B 

Authors: Ying Li a;  Biao Lu a;  Chunhong Li a; Yulin Li a
Affiliation:   a National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou, P.R. China
DOI: 10.1081/SCC-120018704
Publication Frequency: 24 issues per year
Published in: journal Synthetic Communications, Volume 33, Issue 8 January 2003 , pages 1417 - 1423
Subject: Organic Chemistry;
Formats available: HTML (English) : PDF (English)
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Abstract

Hedaol B, a new bisnorditerpene isolated from the Japanese brown alga Sargassum. sp., was first synthesized starting from geranyl acetone, alkylation of silyl cyanide as the key step.
Keywords: Hedaol B; Alkylation; Total synthesis
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