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Glycosylation of Mono- and Bicyclic Dicarbonic Acid Imides
Authors:
E. Schlimme a;
H. Frister a;
K. -P. Raezke a
| Affiliation: | a Institut f r Chemie und Physik, Bundesanstalt fr Milchforschung, Kiel, Federal Republic of Germany |
DOI:
10.1080/07328318808056288
Publication Frequency:
12 issues per year
Published in:
Nucleosides, Nucleotides and Nucleic Acids,
Volume
7,
Issue
5 &
6
October
1988
, pages 577
- 580
Nucleosides, Nucleotides and Nucleic Acids,
Volume
7,
Issue
5 &
6
October
1988
, pages 577
- 580
Subjects:
Drug Design & Development;
Medicinal & Pharmaceutical Chemistry;
Organic Chemistry;
Pharmaceutical Science;
Formats available:
PDF
(English)
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Abstract
Glycosylation of some mono- and bicyclic dicarbonic acid imides was performed via the Friedel-Crafts-catalyzed silyl Hilbert-Johnson reaction. The occurrence of β-N-ribosylation was established by 1H and 13C NMR spectroscopy. The electron distributions in the lactam region of the N-silylated cyclic imides strongly influence the glycosylation. The N-glycosylated cyclic imides are potential agents for glycoalkylation of lysine residues in proteins.
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