Mineralogy and parageneses of Pb oxychlorides in L
ngban-type deposits, Bergslagen, Sweden
Author:
Erik Jonsson ab
| Affiliations: | a Department of Mineralogy, Swedish Museum of Natural History, Stockholm |
| b Department of Geology and Geochemistry, Stockholm University, Stockholm |
DOI:
10.1080/11035890301252087
Publication Frequency:
4 issues per year
Subjects:
Earth Sciences;
Geochemistry;
Geology - Earth Sciences;
Geophysics;
Geotechnical Engineering;
Mining, Mineral & Petroleum Engineering;
Palaeontology;
Paleobiology;
Physical Geography;
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Abstract
The Pb oxychlorides comprise a group of rare minerals occurring as fissure and vein fillings in Palaeoproterozoic L
ngban-type Mn-Fe oxide deposits within the Bergslagen ore province, south central Sweden. Ecdemite, heliophyllite, sahlinite and nadorite occur at Harstigen; sahlinite at Jakobsberg, and all these as well as blixite, freedite, mendipite, perite and sundiusite occur at L ngban. However, the presence of heliophyllite at L ngban is ambiguous. Typical assemblages include ubiquitous calcite and baryte, and minor native metals, hydrocerussite, arsenites, arsenates and silicates. Electron microprobe analyses of a selection of Pb oxychloride minerals from these deposits are presented. These data indicate substitution between Sb3+ and As3+ in the ecdemite (-heliophyllite) and nadorite-type oxychloride structures. Furthermore, the composition of blixite is variable; empirically it varies between c. Pb4O3Cl2 and Pb2O(OH)Cl. The Pb oxychloride assemblages occur in two main textural positions: 1) in partly open fissures or druses, and 2) intergrown in veins or schlieren. Textural and paragenetic observations suggest that the oxychlorides formed at two main stages; firstly associated with metamorphism of the host rocks; secondly at lower P and T during post-metamorphic brittle tectonic conditions. Alteration of oxychlorides may lead to formation of native lead, litharge, hedyphane, Pb carbonates, nadorite and a finnemanite-like phase. The dominant fissure and vein host rocks comprise Fe-Mn-oxide ores or oxide±silicate-bearing carbonate rocks and Fe-Mn skarn rocks. Most of the required metals were probably sequestered from the local host rocks. It is suggested that the fissure-hosted oxychloride assemblages formed primarily from saline aqueous solutions at low pressures and temperatures.
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Keywords:
Lead oxychlorides;
blixite;
ecdemite;
heliophyllite;
mendipite;
nadorite;
sahlinite;
sundiusite;
L ngban;
Bergslagen
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ngban-type Mn-Fe oxide deposits within the Bergslagen ore province, south central Sweden. Ecdemite, heliophyllite, sahlinite and nadorite occur at Harstigen; sahlinite at Jakobsberg, and all these as well as blixite, freedite, mendipite, perite and sundiusite occur at L
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